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Synthesis, Structure and Luminescent Property of Two New 2D Metal‐organic Frameworks containing Lanthanide Ions
Author(s) -
Chen Zhi,
Fang Ming,
Ren Peng,
Li XiuHua,
Zhao Bin,
Wei Shi,
Cheng Peng
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700374
Subject(s) - lanthanide , luminescence , crystal structure , ion , metal organic framework , crystallography , hydrothermal synthesis , materials science , hydrothermal circulation , metal , hydrothermal reaction , metal ions in aqueous solution , diffraction , coordination polymer , polymer , inorganic chemistry , chemistry , chemical engineering , organic chemistry , physics , metallurgy , optoelectronics , adsorption , optics , composite material , engineering
Two novel lanthanide‐based coordination polymers with 2D lattice‐type motif, [Ln 2 (CAM) 3 (H 2 O) 4 ]·2H 2 O (CAM = 4‐Hydroxypyridine‐2,6‐dicarboxylate; Ln = Tb( 1 ), Pr( 2 )), have been prepared by hydrothermal reaction of Ln(OH) 3 , CAM and water at 160 °C and characterized by single‐crystal X‐ray diffraction analysis, IR and TGA. The investigation of luminescent property reveals that 1 exhibits characteristic green emission of Tb 3+ ions.
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