Synthese und Kristallstruktur der spirocyclischen Gallium‐ und Indium‐Chalkogen‐Heterocyclen [(Me 2 Ga) 6 S(SSiMe 3 ) 4 ], [(Me 2 Ga) 6 Se(SeSiMe 3 ) 4 ] und [(Me 2 In) 6 S(SSiMe 3 ) 4 ] | Zendy

Kluge Oliver | Zendy; Puidokait Martin | Zendy; Biedermann Ralf | Zendy; Krautscheid Harald | Zendy

Premium

Synthese und Kristallstruktur der spirocyclischen Gallium‐ und Indium‐Chalkogen‐Heterocyclen [(Me 2 Ga) 6 S(SSiMe 3 ) 4 ], [(Me 2 Ga) 6 Se(SeSiMe 3 ) 4 ] und [(Me 2 In) 6 S(SSiMe 3 ) 4 ]

Author(s) -

Kluge Oliver,

Puidokait Martin,

Biedermann Ralf,

Krautscheid Harald

Publication year - 2007

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200700373

Subject(s) - isostructural , chalcogen , gallium , crystallography , indium , crystal structure , reactivity (psychology) , chemistry , stereochemistry , medicine , organic chemistry , pathology , alternative medicine

Synthesis and Crystal Structures of Spirocyclic Gallium and Indium Chalcogen Heterocycles [(Me 2 Ga) 6 S(SSiMe 3 ) 4 ], [(Me 2 Ga) 6 Se(SeSiMe 3 ) 4 ] and [(Me 2 In) 6 S(SSiMe 3 ) 4 ] The isostructural title compounds [(Me 2 M) 6 E(ESiMe 3 ) 4 ] (M = Ga, In; E = S, Se) crystallize in space group C 2/ c and consist of two M 3 E 3 rings in twist conformation, sharing a common chalcogen atom. The reactivity of the remaining M–CH 3 and E–SiMe 3 bonds can be used for further reactions.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research