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Synthese und Kristallstruktur der spirocyclischen Gallium‐ und Indium‐Chalkogen‐Heterocyclen [(Me 2 Ga) 6 S(SSiMe 3 ) 4 ], [(Me 2 Ga) 6 Se(SeSiMe 3 ) 4 ] und [(Me 2 In) 6 S(SSiMe 3 ) 4 ]
Author(s) -
Kluge Oliver,
Puidokait Martin,
Biedermann Ralf,
Krautscheid Harald
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700373
Subject(s) - isostructural , chalcogen , gallium , crystallography , indium , crystal structure , reactivity (psychology) , chemistry , stereochemistry , medicine , organic chemistry , pathology , alternative medicine
Synthesis and Crystal Structures of Spirocyclic Gallium and Indium Chalcogen Heterocycles [(Me 2 Ga) 6 S(SSiMe 3 ) 4 ], [(Me 2 Ga) 6 Se(SeSiMe 3 ) 4 ] and [(Me 2 In) 6 S(SSiMe 3 ) 4 ] The isostructural title compounds [(Me 2 M) 6 E(ESiMe 3 ) 4 ] (M = Ga, In; E = S, Se) crystallize in space group C 2/ c and consist of two M 3 E 3 rings in twist conformation, sharing a common chalcogen atom. The reactivity of the remaining M–CH 3 and E–SiMe 3 bonds can be used for further reactions.