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Influence of Secondary Bonds on the Network Assembly and Property in Lead(II) 3‐Sulfobenzoate Coordination Polymer
Author(s) -
Miao XiaoHe,
Zhu LongGuan
Publication year - 2008
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700363
Subject(s) - coordination polymer , elemental analysis , polymer , fluorescence , chemistry , crystallography , crystal structure , ethylene , single crystal , hydrothermal circulation , materials science , inorganic chemistry , organic chemistry , chemical engineering , catalysis , physics , quantum mechanics , engineering
A unique 3‐D Pb II coordination polymer containing ligands 1,2‐bis(4‐pyridyl)ethylene (bpe) and 3‐sulfobenzoate (3‐sb), [Pb(3‐sb)(bpe) 0.5 ] n ( 1 ) has been synthesized by hydrothermal reaction and characterized by elemental analysis, IR, TGA, 1 H NMR, powder X‐ray analysis, and fluorescent spectrum. The single‐crystal X‐ray analysis shows that eight coordination bonds can be divided as five primary bonds and three secondary bonds. The secondary bonds largely enhance the solid stability and provide a high‐dimensional network assembly. The complex also displays strong fluorescent property.