Attempted Abstraction of the Halogenides in (HNEt 3 )[Re(CH 3 CN) 2 Cl 4 ] and Crystal Structures of  cis‐ [Re(CH 3 CN) 2 Cl 4 ]·CH 3 CN and  cis‐ [Re(NHC(OCH 3 )CH 3 ) 2 Cl 4 ] | Zendy

Kunz Peter C. | Zendy; Kurz Philipp | Zendy; Spingler Bernhard | Zendy; Alberto Roger | Zendy

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Attempted Abstraction of the Halogenides in (HNEt 3 )[Re(CH 3 CN) 2 Cl 4 ] and Crystal Structures of cis‐ [Re(CH 3 CN) 2 Cl 4 ]·CH 3 CN and cis‐ [Re(NHC(OCH 3 )CH 3 ) 2 Cl 4 ]

Author(s) -

Kunz Peter C.,

Kurz Philipp,

Spingler Bernhard,

Alberto Roger

Publication year - 2007

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200700265

Subject(s) - solvent , chemistry , solid state , crystal structure , thallium , crystallography , abstraction , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry , philosophy , epistemology

The abstraction of the halogenide ligands in [Re(CH 3 CN) 2 Cl 4 ] − should result in a solvent‐only stabilized Re III complex. The reactions of salts of [Re(CH 3 CN) 2 Cl 4 ] − with silver(I) and thallium(I) salts were investigated and the solid‐state structures of cis‐ [Re(CH 3 CN) 2 Cl 4 ]·CH 3 CN and cis‐ [Re(NHC(OCH 3 )CH 3 ) 2 Cl 4 ] are described.

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