Metal Complexes with a New Ethyl Acetate Pendant‐Armed Macrocyclic Ligand – Crystal Structures of [MnL](ClO 4 ) 2  and [NiL](ClO 4 ) 2 ·CH 3 CN | Zendy

LópezDeber M. | Zendy; Bastida de la Calle R. | Zendy; Macías A. | Zendy; PérezLourido P. | Zendy; Rodríguez A. | Zendy; Valencia Matarranz L. | Zendy

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Metal Complexes with a New Ethyl Acetate Pendant‐Armed Macrocyclic Ligand – Crystal Structures of [MnL](ClO 4 ) 2 and [NiL](ClO 4 ) 2 ·CH 3 CN

Author(s) -

LópezDeber M.,

Bastida de la Calle R.,

Macías A.,

PérezLourido P.,

Rodríguez A.,

Valencia Matarranz L.

Publication year - 2007

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200700224

Subject(s) - chemistry , perchlorate , ligand (biochemistry) , transition metal , metal , crystal structure , infrared spectroscopy , single crystal , crystallography , elemental analysis , coordination complex , inorganic chemistry , ion , organic chemistry , catalysis , biochemistry , receptor

A new ligand, L, bearing two ethyl acetate pendant groups has been synthesized by reaction of the precursor ligand L A with ethylbromoacetate. The coordination capability towards transition [Mn 2+ , Ni 2+ ], post‐transitional [Zn 2+ and Cd 2+ ] and Pb 2+ ions has been investigated starting from the hydrated perchlorate salts of the metals. The new ligand L and the metal complexes obtained were characterized by elemental analysis, FAB MS, conductivity measurements, magnetic studies, IR, UV‐vis and 1 H and 13 C NMR spectroscopy. Furthermore, the crystal structures of the complexes [MnL](ClO 4 ) 2 and [NiL](ClO 4 ) 2 ·CH 3 CN were determined.

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