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A Stable η 2 ‐Bonded Diazoalkane Complex
Author(s) -
Schaub Thomas,
Radius Udo
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700203
Subject(s) - chemistry , inert gas , nitrogen , thermal stability , inert , atmosphere (unit) , crystallography , stereochemistry , organic chemistry , physics , thermodynamics
Abstract The synthesis and structural characterization of the new complexes [Ni( i Pr 2 Im) 2 (η 2 ‐ C,C ‐Me 2 C=CHCOMe)] ( 2 ), [Ni( i Pr 2 Im) 2 (η 2 ‐H 2 C=CH‐(4‐C 5 H 4 N)] ( 3 ) and [Ni( i Pr 2 Im) 2 (η 2 ‐ N,N ′‐N 2 CPh 2 )] ( 4 ) is reported. Complex 4 is remarkably stable under an inert gas atmosphere and does not undergo nitrogen loss under thermal or photochemical conditions.