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(Me 2 NH 2 )[(Ph 3 Sn) 3 (MoO 4 ) 2 ], ein Triorganozinnmolybdat mit Schichtstruktur
Author(s) -
Kondracka Małgorzata,
Merzweiler Kurt
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700163
Subject(s) - molybdate , crystallography , crystal structure , acetonitrile , chemistry , ion , molybdenum , x ray crystallography , inorganic chemistry , diffraction , physics , organic chemistry , chromatography , optics
(Me 2 NH 2 )[(Ph 3 Sn) 3 (MoO 4 ) 2 ], a Triorganotin Molybdate with Layer Structure The reaction of [(Ph 3 Sn) 2 MoO 4 ] with (Me 2 NH 2 )Cl in an acetonitrile/water mixture leads to the formation of (Me 2 NH 2 )[(Ph 3 Sn) 3 (MoO 4 ) 2 ] ( 1 ). ( 1 ) crystallizes in the space group Pca2 1 with a = 1967.0(4), b = 1353.1(2) and c = 2176.6(5) pm. In the crystal structure of 1 Ph 3 SnO 2 bipyramides and MoO 4 tetrahedra are linked by corner sharing to give a layer structure. Additionally the layers are connected by O···H···N hydrogen bridges between MoO 4 groups and [Me 2 NH 2 ] + ions to give a 3D network structure.