Reaktion von ( R,R )‐( N,N′ )‐Diisopropylcyclohexyl‐1,2‐diamin mit Me 2 MCl (M = Ga, In) | Zendy

Chamazi Navabeeh Nami | Zendy; Heravi Majid M. | Zendy; Breyhan Thees | Zendy; Neumüller Bernhard | Zendy

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Reaktion von ( R,R )‐( N,N′ )‐Diisopropylcyclohexyl‐1,2‐diamin mit Me 2 MCl (M = Ga, In)

Author(s) -

Chamazi Navabeeh Nami,

Heravi Majid M.,

Breyhan Thees,

Neumüller Bernhard

Publication year - 2007

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200700128

Subject(s) - diamine , toluene , chemistry , salt (chemistry) , boiling , spectroscopy , medicinal chemistry , crystallography , polymer chemistry , organic chemistry , physics , quantum mechanics

Reaction of ( R,R )‐( N,N′ )‐Diisopropylcyclohexyl‐1,2‐diamine with Me 2 MCl (M = Ga, In) ( R,R )‐( N,N′ )‐Diisopropylcyclohexyl‐1,2‐diamine (H 2 L) was reacted with Me 2 GaCl and Me 2 InCl in boiling toluene, respectively. In both cases the salt [Me 2 M(H 2 L)][Me 2 MCl 2 ] [M = Ga ( 1 ), In ( 2 )] was formed. 1 and 2 were characterized by NMR and vibrational spectroscopy. In addition, an X‐ray structure determination was applied on 2 . According to the spectroscopical and structural findings 1 and 2 consist of cations [Me 2 M(H 2 L)] + and anions [Me 2 MCl 2 ] − .

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