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The Monomerization of a Binuclear Molybdenum(VI) Dioxo Complex by an Unusual Silylation Reaction
Author(s) -
Ma Xiaoli,
Yang Zhi,
Schulzke Carola,
Ringe Arne,
Magull Jörg
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700125
Subject(s) - molybdenum , chemistry , silylation , chloromethane , methanol , medicinal chemistry , polymer chemistry , photochemistry , organic chemistry , catalysis
The formation of a mononuclear molybdenum(VI) complex [MoO 2 {O(CH 2 ) 2 S(CH 2 ) 2 OH}(OSiBu t Ph 2 )] ( 2 ) derived from its binuclear precursor [MoO 2 {O(CH 2 ) 2 S(CH 2 ) 2 O}] 2 ( 1 ) by a silylation reaction accompanied by the conversion of methanol to chloromethane is reported.
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