{[Mn 2 (μ 3 ‐Tda) 2 (μ‐H 2 O)(H 2 O) 2 (bipy)]·DMF} n  – a 2D Manganese(II) Coordination Polymer involving Six‐membered Binuclear Metallacycle Nodes | Zendy

Cheng YaQian | Zendy; Xiao HongPing | Zendy; Li XinHua | Zendy; Wang JiaGuo | Zendy; Morsali Ali | Zendy

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{[Mn 2 (μ 3 ‐Tda) 2 (μ‐H 2 O)(H 2 O) 2 (bipy)]·DMF} n – a 2D Manganese(II) Coordination Polymer involving Six‐membered Binuclear Metallacycle Nodes

Author(s) -

Cheng YaQian,

Xiao HongPing,

Li XinHua,

Wang JiaGuo,

Morsali Ali

Publication year - 2007

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200700117

Subject(s) - manganese , carboxylate , crystallography , chemistry , ion , crystal structure , polymer , inorganic chemistry , stereochemistry , organic chemistry

The single crystal X‐ray analysis of a novel thiophene‐2,5‐dicarboxylic acid (H 2 Tda) Manganese(II) coordination polymer, {Mn 2 (μ 3 ‐Tda) 2 (μ‐H 2 O)(H 2 O) 2 (bipy)]·DMF} n , shows two different types of Mn 2+ ‐ions with environment of Mn1O 6 and Mn2O 4 N 2 , and the complex is a two‐dimensional polymer as a result of bridging (Tda) 2− ligands and by connecting the carboxylate‐ and water‐bridged {Mn 2 (μ‐Tda) 2 (μ‐H 2 O)} nodes.

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