Preparation and Structure of [Me 3 N(CF 3 ) 2 BCCB(CF 3 ) 2 NMe 3 ] | Zendy

Brauer David J. | Zendy; Pawelke Gottfried | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Preparation and Structure of [Me 3 N(CF 3 ) 2 BCCB(CF 3 ) 2 NMe 3 ]

Author(s) -

Brauer David J.,

Pawelke Gottfried

Publication year - 2007

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200700077

Subject(s) - trifluoromethyl , borane , trimethylamine , chemistry , molecule , crystallography , boron , atom (system on chip) , stereochemistry , medicinal chemistry , organic chemistry , catalysis , alkyl , computer science , embedded system

Bis‐trimethylamine‐ethynyl‐di‐bis(trifluoromethyl)borane [Me 3 N(CF 3 ) 2 BCCB(CF 3 ) 2 NMe 3 ] ( 1 ) has been prepared from trimethylamine‐ethynyl‐bis(trifluoromethyl)borane, [HCCB(CF 3 ) 2 NMe 3 ], and dimethylamino‐bis(trifluoromethyl)borane, (CF 3 ) 2 BNMe 2 . The structure of 1 has been determined by x‐ray crystallography. In the solid state the molecule possesses crystallographic C i symmetry. The acetylenic attachment to the boron atom is characterized by a short B–C bond length of 1.565(4) Å and an essentially linear B–C–C′ bond angle of 178.1(4)°.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research