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Synthesis and Crystal Structure of a Novel Polymeric Lead(II) Compound: [Pb 2 (phen) 2 (N 3 ) 3 (ClO 4 )] n
Author(s) -
Marandi Farzin,
Mirtamizdoust Babak,
Chantrapromma Suchada,
Fun HoongKun
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700076
Subject(s) - crystallography , stacking , crystal structure , supramolecular chemistry , chemistry , coordination number , single crystal , ion , infrared spectroscopy , stereochemistry , organic chemistry
A 2D lead(II) coordination polymer [Pb 2 (phen) 2 (N 3 ) 3 (ClO 4 )] n ,( 1 ) containing 1,10‐phenanthroline (phen) and two different anions, has been synthesized and characterized by elemental analysis, IR and 1 H NMR spectroscopy and X‐ray crystallography. The single‐crystal X‐ray data show two different kinds of Pb 2+ ions with coordination numbers of eight, Pb1 = PbN 6 O 2 and Pb2 = PbN 8 , with hemidirected and holodirected structures, respectively. The supramolecular features in 1 is negiotated through the weak but directional C‐H···O and C‐H···N interactions and aromatic π–π stacking interactions.