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The Structure of Tris(trifluoromethyl)tellurium Fluoride Dimethylformamide, $\rm [Te(CF_{3})_{3} \times DMF(\mu-F)]{\infty}$
Author(s) -
Kirij Natalya V.,
Yagupolskii Yurii L.,
Tyrra Wieland,
Pantenburg Ingo,
Naumann Dieter
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200700038
Subject(s) - trifluoromethyl , tellurium , fluorine , chemistry , tris , dimethylformamide , fluoride , crystallography , bridging (networking) , derivative (finance) , group (periodic table) , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry , computer network , biochemistry , alkyl , solvent , computer science , financial economics , economics
$\rm [Te(CF_{3})_{3} \times DMF(\mu-F)]{\infty}$ represents the first structurally characterized example of a trifluoromethyl main group element compound with more than 8‐N (where N is the main group number) perfluoroalkyl groups and also the first fluoro(triorgano)tellurium derivative. Its polymeric nature is caused by asymmetric bridging fluorine atoms forming infinite chains.