Synthesis, Structure and Magnetic Properties of a Novel Nickel(II) Radical Heterospin Complex with Salicylaldoxime | Zendy

Ma Yue | Zendy; Zhang Wei | Zendy; Xu GongFeng | Zendy; Yoshimura Kazuyoshi | Zendy; Liao DaiZheng | Zendy; Jiang ZongHui | Zendy; Yan ShiPing | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis, Structure and Magnetic Properties of a Novel Nickel(II) Radical Heterospin Complex with Salicylaldoxime

Author(s) -

Ma Yue,

Zhang Wei,

Xu GongFeng,

Yoshimura Kazuyoshi,

Liao DaiZheng,

Jiang ZongHui,

Yan ShiPing

Publication year - 2007

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200700012

Subject(s) - intramolecular force , chemistry , antiferromagnetism , nickel , hydrogen bond , intermolecular force , crystallography , polymer chemistry , stereochemistry , molecule , organic chemistry , physics , condensed matter physics

A novel heterospin complex containing both Ni II and nitroxide radical ligands: [Ni(salox) 2 (NIT4Py) 2 ] ( 1 ) (salox = salicylaldoxime, NIT4Py = 2‐(4′‐pyridyl)‐4,4,5,5‐ tetramethyl‐imidazoline‐1‐oxyl‐3‐oxide) has been synthesized and structurally characterized. The structure consists of neutral Ni(salox) 2 (NIT4Py) 2 moieties bridged by intermolecular hydrogen bonds, forming a one‐dimensional chain structure. Magnetic measurements show intramolecular antiferromagnetic interactions between NIT4Py and Ni 2+ ion.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research