Premium
Synthesis, Crystal Structure and Supramolecular Organization of the 1D Coordination Polymer [Cu(HCOO) 2 (4‐bpytm)], (4‐bpytm = Bis(4‐pyridylthio)methane)
Author(s) -
Carballo Rosa,
Covelo Berta,
GarcíaMartínez Emilia,
Lago Ana B.,
VázquezLópez Ezequiel M.
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600395
Subject(s) - ligand (biochemistry) , supramolecular chemistry , coordination polymer , chemistry , denticity , methane , stereochemistry , hydrogen bond , crystal structure , crystallography , organic chemistry , molecule , receptor , biochemistry
The reaction of the flexible pyridyl dithioether ligand Bis(4‐pyridylthio)methane (4‐bpytm) with copper(II) formiate led to the formation of the coordination polymer [Cu(HCOO) 2 (4‐bpytm)] n , which has been characterized structurally. The copper atom is in a square‐planar environment and 4‐bpytm acts as an N,N′‐bis(monodentate) bridging ligand creating an onedimensional polymeric arrangement. The formiate ligand plays a key role in the supramolecular organization of the chains via CH formiate …O formiate and CH 4bpytm …O formiate hydrogen bonds.