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Synthese und Kristallstrukturen von [p‐Me 3 NC 6 H 4 HgOC(O)Me][MeOSO 3 ] und [(p‐Me 3 NC 6 H 4 ) 2 Hg][HgI 4 ]
Author(s) -
Kuhn Norbert,
AbuSalem Qutaiba,
MaichleMößmer Cäcilia,
Steimann Manfred
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600372
Subject(s) - crystal structure , crystallography , chemistry , carbene , stereochemistry , catalysis , biochemistry
Syntheses and Crystal Structures of [p‐Me 3 NC 6 H 4 HgOC(O)Me][MeOSO 3 ] and [(p‐Me 3 NC 6 H 4 ) 2 Hg][HgI 4 ] The carbene complexes [p‐Me 3 NC 6 H 4 HgOC(O)CH 3 ][MeOSO 3 ] ( 5 ) and [(p‐Me 3 NC 6 H 4 ) 2 Hg][HgI 4 ] ( 7 ) are obtained by alkylation of Me 2 NC 6 H 4 HgOC(O)Me ( 4 ) with Me 2 SO 4 or MeI. The crystal structures of 5 and 7 reveal the expected presence of Hg‐C single bonds in both complexes.