Synthese und Kristallstrukturen von [p‐Me 3 NC 6 H 4 HgOC(O)Me][MeOSO 3 ] und [(p‐Me 3 NC 6 H 4 ) 2 Hg][HgI 4 ] | Zendy

Kuhn Norbert | Zendy; AbuSalem Qutaiba | Zendy; MaichleMößmer Cäcilia | Zendy; Steimann Manfred | Zendy

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Synthese und Kristallstrukturen von [p‐Me 3 NC 6 H 4 HgOC(O)Me][MeOSO 3 ] und [(p‐Me 3 NC 6 H 4 ) 2 Hg][HgI 4 ]

Author(s) -

Kuhn Norbert,

AbuSalem Qutaiba,

MaichleMößmer Cäcilia,

Steimann Manfred

Publication year - 2007

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200600372

Subject(s) - crystal structure , crystallography , chemistry , carbene , stereochemistry , catalysis , biochemistry

Syntheses and Crystal Structures of [p‐Me 3 NC 6 H 4 HgOC(O)Me][MeOSO 3 ] and [(p‐Me 3 NC 6 H 4 ) 2 Hg][HgI 4 ] The carbene complexes [p‐Me 3 NC 6 H 4 HgOC(O)CH 3 ][MeOSO 3 ] ( 5 ) and [(p‐Me 3 NC 6 H 4 ) 2 Hg][HgI 4 ] ( 7 ) are obtained by alkylation of Me 2 NC 6 H 4 HgOC(O)Me ( 4 ) with Me 2 SO 4 or MeI. The crystal structures of 5 and 7 reveal the expected presence of Hg‐C single bonds in both complexes.

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