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O ‐Triorganosilyl Carbamoselenoates – Synthesis and Reactions
Author(s) -
Ibi Kazumasa,
Kawai Kohji,
Kato Shinzi,
Ando Fumio,
Koketsu Jugo
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600368
Subject(s) - tin , alkali metal , silylation , halide , germanium , potassium , sodium , chemistry , germanium compounds , group (periodic table) , inorganic chemistry , medicinal chemistry , organic chemistry , catalysis , silicon
A series of O ‐triorganosilyl carbamoselenoates were isolated in good yields from the reaction of sodium or potassium carbamoselenoates with triorganosilyl chlorides. The O ‐silyl carbamoselenoates readily reacted with RbF and CsF and with organo‐germanium, ‐tin, and ‐lead halides and gave the corresponding heavy alkali metal and Se ‐substituted Group 14 organometal and carbamoselenoates in moderate to good yields.