Crystal Structure of the New Cobalt Tellurite Chloride Co 5 Te 4 O 11 Cl 4 | Zendy

Becker Richard | Zendy; Johnsson Mats | Zendy; Berger Helmuth | Zendy

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Crystal Structure of the New Cobalt Tellurite Chloride Co 5 Te 4 O 11 Cl 4

Author(s) -

Becker Richard,

Johnsson Mats,

Berger Helmuth

Publication year - 2007

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200600336

Subject(s) - triclinic crystal system , crystallography , lone pair , halide , crystal structure , van der waals force , polyhedron , chemistry , crystal (programming language) , molecule , cobalt , group (periodic table) , inorganic chemistry , geometry , mathematics , computer science , programming language , organic chemistry

The crystal structure of the new compound Co 5 Te 4 O 11 Cl 4 is described. It crystallizes in the triclinic system, space group P‐1 with the unit cell parameters a = 822.26(8) pm, b = 1029.7(1) pm, c = 1031.1(1) pm, α = 110.80(1)°, β = 97.950(9)°, γ = 98.260(9)° and Z = 2. The structure is layered along the bc–plane and built by [CoO 5 Cl], [CoO 4 Cl 2 ] and [CoO 4 Cl] polyhedra sandwiched by [TeO 3 E ] and [TeO 4 E ] polyhedra. The layers can be regarded as infinite molecules without any net charge and only weak van der Waals forces connect them to each other. The halides and the lone‐pair, E , of Te IV protrude from the layers.

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