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Synthetic and Structural Studies of Lead and Bismuth Organohalides Bearing a β ‐Diketiminato Ligand
Author(s) -
Pineda Leslie W.,
Jancik Vojtech,
Nembenna Sharanappa,
Roesky Herbert W.
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600325
Subject(s) - bismuth , chemistry , halide , ligand (biochemistry) , salt (chemistry) , inorganic chemistry , crystallography , single crystal , crystal structure , organic chemistry , receptor , biochemistry
Two novel organohalides of lead and bismuth supported by a ß‐diketiminato ligand are reported. Salt elimination reactions of the β‐diketiminatolithium salt and the corresponding lead and bismuth halides led to the isolation of lead [{HC(CMeNAr) 2 }PbBr] ( 2 ; Ar = 2,6‐ i Pr 2 C 6 H 3 ) and bismuth [{HC(Et 2 NCH 2 CH 2 NCMe) 2 }BiCl 2 ] ( 4 ), respectively. These new compounds have been characterized by spectrometric and elemental analyses, and the solid‐state structures have been determined by single‐crystal X‐ray structural analysis.