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Synthese und Charakterisierung von Methyldialkoxogallanen MeGa(OR) 2 (R = Et, n Bu)
Author(s) -
Chamazi Navabeeh Nami,
Heravi Majid M.,
Neumüller Bernhard
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600306
Subject(s) - mega , chemistry , toluene , stereochemistry , physics , organic chemistry , astronomy
Synthesis and Characterization of Methyldialkoxogallanes MeGa(OR) 2 (R = Et, n Bu) GaMe 3 reacts with ROH (R = Et, n Bu) to give the methyldialkoxogallanes MeGa(OR) 2 [R = Et ( 1 ), n Bu ( 2 )] under evolution of methane in boiling toluene. 1 and 2 were characterized by NMR and IR spectroscopy as well as by X‐ray analyses. According to the structural investigations both compounds form centrosymmetrical dimers which are connected to infinite chains along [100] ( 1 ) or [001] ( 2 ).