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Synthesis and Crystal Structures of Octahedral Metal Complexes containing the New Dianion [PhP(Se,O)Se‐Se(O,Se)PPh] 2−
Author(s) -
Shi Weifeng,
Zhang Le,
ShafaeiFallah Maryam,
Rothenberger Alexander
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600297
Subject(s) - chemistry , octahedron , reagent , metal , selenium , crystal structure , crystallography , medicinal chemistry , organic chemistry
The synthesis and structures of three new compounds are reported. [Mg 2 {PhP(Se,O)Se‐Se(O,Se)PPh} 2 (thf) 7 (H 2 O) 3 ] ( 1 ), [Mg{PhP(Se,O)Se‐Se(O,Se)PPh}(thf) 3 (H 2 O)] ( 2 ), and [Mn{PhP(Se,O)Se‐Se(O,Se)PPh}(thf) 3 (H 2 O)] ( 3 ) were prepared by treatment of Woollins' reagent [PhP(Se)(μ‐Se)] 2 with the corresponding hydrated metal acetates.