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The 3D Supramolecular Compound {[Cu 2 (L‐val) 2 (4,4′‐bipy)(H 2 O) 2 ](NO 3 ) 2 } n (L‐val = L‐valine anion, 4,4′‐bipy = 4,4′‐bipyridine)
Author(s) -
Lou Benyong,
Huang Xiaodong,
Lin Xiangchao
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600295
Subject(s) - crystallography , molecule , supramolecular chemistry , x ray crystallography , crystal structure , chemistry , ion , inorganic chemistry , diffraction , materials science , physics , organic chemistry , optics
{[Cu 2 (L‐val) 2 (4,4′‐bipy)(H 2 O) 2 ](NO 3 ) 2 } n was synthesized and its crystal structure was determined by X‐ray diffraction. In the presence of 4,4′‐bipyridine, deprotoned L‐valine chelates Cu II ions into coordination layers which were linked into a framework by hydrogen‐bonded chains resulting from nitrate anions and water molecules.