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IR‐Spektren 15 N‐isotopenmarkierter Nitrido‐, Chlorthionitreno‐ und Cyclothiazeno‐Komplexe von Molybdän, Wolfram und Rhenium
Author(s) -
Dietrich Armin,
Dehnicke Kurt
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600294
Subject(s) - rhenium , molybdenum , chemistry , tungsten , infrared spectroscopy , nitrogen , metal , crystallography , ring (chemistry) , polymer chemistry , stereochemistry , inorganic chemistry , organic chemistry
Abstract IR Spectra of 15 N Labelled Nitrido, Chlorothionitreno and Cyclothiazeno Complexes of Molybdenum, Tungsten and Rhenium The IR spectra of selected, 15 N labelled complexes of molybdenum, tungsten, and rhenium with metal‐nitrogen multiple bonds are reported. The examined compounds include nitrido complexes ( I ), chlorothionitreno complexes ( II ), and cyclo ‐thiazeno complexes ( III ): The results of IR spectroscopy allow reliable assignments of characteristic vibrational modes for the types I and II , whereas the assignments of vibrational modes of compounds of type III are influenced by MN 3 S 2 ring vibrations.