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Bis(2,4,6‐trimethylphenyl)tellurium(IV) Dicyanide: the First Crystal Structure for a Tellurium Cyanide of the Type R 2 Te(CN) 2
Author(s) -
Klapötke Thomas M.,
Krumm Burkhard,
Scherr Matthias,
Schwab Ingo
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600283
Subject(s) - tellurium , cyanide , chemistry , crystal structure , crystal (programming language) , type (biology) , trimethylsilyl cyanide , crystallography , stereochemistry , inorganic chemistry , catalysis , organic chemistry , biology , computer science , programming language , ecology
The reaction of Mes 2 TeF 2 (Mes = 2,4,6‐trimethylphenyl) with trimethylsilyl cyanide yields the corresponding tellurium(IV) dicyanide Mes 2 Te(CN) 2 . Isolation of suitable crystals allows the determination of the first crystal structure of a compound of the type R 2 Te(CN) 2 .