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How Common Are True Aminopyridinato Complexes?
Author(s) -
Deeken Stefan,
Motz Günter,
Kempe Rhett
Publication year - 2007
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600269
Subject(s) - ruthenium , pyridine , lanthanide , transition metal , chemistry , crystallography , crystal structure , medicinal chemistry , organic chemistry , catalysis , ion
An overview over the binding situation in transition metal and lanthanide aminopyridinato complexes is given. True aminopyridinato complexes in which we observe a significant longer N‐amido than N‐pyridine bond length are rare and for instance observed for ruthenium. Additional examples of ruthenium aminopyridinato complexes were synthesized and characterized by X‐ray crystal structure analysis.

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