An Ortho‐silicate‐hydroxide: Rb 5 [SiO 4 ][OH] | Zendy

Kerp Oliver | Zendy; Möller Angela | Zendy

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An Ortho‐silicate‐hydroxide: Rb 5 [SiO 4 ][OH]

Author(s) -

Kerp Oliver,

Möller Angela

Publication year - 2007

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200600247

Subject(s) - silicate , trigonal crystal system , crystallography , tetrahedron , crystal structure , group (periodic table) , hydroxide , space group , structure type , materials science , chemistry , mineralogy , x ray crystallography , inorganic chemistry , diffraction , physics , optics , organic chemistry

Rb 5 [SiO 4 ][OH] crystallizes in the monoclinc space group C2/m with a = 737.3(1) pm, b = 1073.7(2) pm, c = 1207.2(2) pm, β = 106.07(2)° and Z = 4 (single crystal data; R1= 0.0681 all data). Layers of edge‐connected distorted trigonal prismatic [(OH)Rb 6 ] entities and isolated tetrahedral [SiO 4 ] units present the main structural features of this unprecedented structure type.

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