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Synthesis, Characterization, and Crystal Structure of a New Coordination Polymer of Lead(II) Containing 2,6‐Pyridinedicarboxylic Acid
Author(s) -
Rafizadeh Masoud,
Amani Vahid,
Neumüller Bernhard
Publication year - 2006
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600218
Subject(s) - monoclinic crystal system , crystal structure , coordination polymer , crystallography , infrared spectroscopy , characterization (materials science) , polymer , single crystal , chemistry , elemental analysis , crystal (programming language) , materials science , inorganic chemistry , nanotechnology , organic chemistry , computer science , programming language
Abstract The reaction of solution 2,6‐pyridinedicarboxylic acid ( 1 ) and 2,2′‐Bipyridine with Pb(NO 3 ) 2 led to the coordination polymer [Pb(pydc)] n ( 2 ) (pydcH 2 is 2,6‐pyridinedicarboxylic acid). This complex was characterized by elemental analysis, IR spectroscopy and single‐crystal structure of 2 . Crystal data for 2 at −80 °C: monoclinic, space group P2 1 /n, a = 977.2(1), b = 554.0(1), c = 1425.3(2) pm, β = 104.75(1)°, Z = 4, R 1 = 0.0261. The units [Pb(pydc)] form infinite chains along [010].