Structural Consequences of S → Se Substitution in some Symmetrical [M(S 2 CNR 2 ) 3 ] Complexes | Zendy

Dietzsch Wolfgang | Zendy; Duffy Norman V. | Zendy; Lee Aaron M. | Zendy; Skelton Brian W. | Zendy; White Allan H. | Zendy

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Structural Consequences of S → Se Substitution in some Symmetrical [M(S 2 CNR 2 ) 3 ] Complexes

Author(s) -

Dietzsch Wolfgang,

Duffy Norman V.,

Lee Aaron M.,

Skelton Brian W.,

White Allan H.

Publication year - 2006

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200600207

Subject(s) - chemistry , crystallography , chelation , metal , alkyl , crystal structure , substitution (logic) , stereochemistry , inorganic chemistry , organic chemistry , computer science , programming language

The consequences of replacement of the symmetrically chelate ligands in [M(E 2 CNR 2 ) 3 ] (E = S, Se) complexes of potential 32 symmetry by analogous mixed S,Se unsymmetrical chelates are explored for both small (M = Co) and large (M = In) metal atoms, and R = primary (Et) and secondary ( i Pr) alkyl substituents by way of low‐temperature single crystal X‐ray studies of [(Co(SSeCNEt 2 ) 3 ] ([Co(Se 2 CNEt 2 ) 3 ] also determined as datum), and [In(SSeCNR 2 ) 3 ], R = Et, i Pr. The structure of [( i Pr 2 N·CS·Se) 2 ] is also recorded.

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