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MnO 3 Cl, Isolation and Crystal Structure
Author(s) -
Spandl Johann,
Supeł Joanna,
Drews Thomas,
Seppelt Konrad
Publication year - 2006
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600186
Subject(s) - crystal structure , crystallography , intermolecular force , raman spectroscopy , molecule , chemistry , crystal (programming language) , bond length , physics , organic chemistry , programming language , computer science , optics
MnO 3 Cl is prepared from KMnO 4 und ClSO 3 H. The thermally very unstable compound is identified by its Raman spectrum and a single crystal structure determination: a = 715.4(5), b = 1008.3(7), c = 500.9(4) pm, space group Cmc2 1 . Solid MnO 3 Cl consists of molecules with only weak intermolecular interactions. The M–Cl bond length is 209.9(4) pm. The crystal structure is compared to those of MnO 3 F, CrO 2 Cl 2 , and ReO 3 Cl, the X‐ray crystal structure determinations of which are also submitted in this article.