Sm 2 Se 5 O 13 : A Selenite–Diselenite according to Sm 2 (SeO 3 )(Se 2 O 5 ) 2 | Zendy

Wickleder Mathias S. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Sm 2 Se 5 O 13 : A Selenite–Diselenite according to Sm 2 (SeO 3 )(Se 2 O 5 ) 2

Author(s) -

Wickleder Mathias S.

Publication year - 2006

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200600172

Subject(s) - monoclinic crystal system , ampoule , crystallography , selenium , crystal structure , ion , lone pair , materials science , chemistry , analytical chemistry (journal) , molecule , organic chemistry , metallurgy , chromatography

Pale yellow single crystals of Sm 2 (SeO 3 )(Se 2 O 5 ) 2 (monoclinic, P 2 1 / c , Z = 4, a = 1003.6(2), b = 1022.5(2), c = 1287.3(2) pm, β = 112.3(2)°) were obtained from the reaction of Sm 2 O 3 and SeO 2 at 350 °C in a sealed glass ampoule. In the crystal structure both Se 2 O 5 2− and SeO 3 2− groups connect the Sm 3+ ions into layers. Between the layers the lone electron pairs of the anions are located.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research