A Section Through the Compositional Triangle Pr‐Co‐I at 600 °C: Pr 7 CoI 12  and Pr 2 Co 2 I | Zendy

Palasyuk Andriy | Zendy; Pantenburg Ingo | Zendy; Meyer Gerd | Zendy

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A Section Through the Compositional Triangle Pr‐Co‐I at 600 °C: Pr 7 CoI 12 and Pr 2 Co 2 I

Author(s) -

Palasyuk Andriy,

Pantenburg Ingo,

Meyer Gerd

Publication year - 2006

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200600152

Subject(s) - crystallography , section (typography) , hexagonal crystal system , trigonal crystal system , bar (unit) , crystal (programming language) , crystal structure , materials science , physics , chemistry , computer science , programming language , operating system , meteorology

At 600 °C, two phases exist in equilibrium in the system Pr–Co–I, Pr 7 CoI 12 and Pr 2 Co 2 I, the former with isolated {Pr 6 Co} clusters, the latter with Pr–Co–Pr slabs. The crystal structures were determined from single‐crystal X‐ray data: Pr 7 CoI 12 : trigonal, $R{\bar 3}$ (no. 148), a = 1581.62(10), c = 1079.18(7) pm, Z = 3, R = 0.0493 for all data; Pr 2 Co 2 I: hexagonal, P6 3 /mmc (no. 194), a = 403.86(4), c = 1743.4(2) pm, Z = 2. R = 0.1196 for all data.

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