Facile Routes to Sodium Tetradecaphosphide Na 4 P 14  and Molecular Structure of Na 4 (DME) 7.5 P 14  and Na 4 (en) 6 P 14  (DME = 1,2‐dimethoxyethane; en = ethylenediamine) | Zendy

Miluykov Vasili | Zendy; Kataev Alexander | Zendy; Sinyashin Oleg | Zendy; Lönnecke Peter | Zendy; HeyHawkins Evamarie | Zendy

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Facile Routes to Sodium Tetradecaphosphide Na 4 P 14 and Molecular Structure of Na 4 (DME) 7.5 P 14 and Na 4 (en) 6 P 14 (DME = 1,2‐dimethoxyethane; en = ethylenediamine)

Author(s) -

Miluykov Vasili,

Kataev Alexander,

Sinyashin Oleg,

Lönnecke Peter,

HeyHawkins Evamarie

Publication year - 2006

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200600108

Subject(s) - ethylenediamine , dimethoxyethane , sodium , chemistry , inorganic chemistry , organic chemistry , electrode , electrolyte

Tetrasodium tetradecaphosphide Na 4 P 14 was obtained either from the reaction of PCl 3 with sodium in refluxing THF or from the reaction of red phosphorus and sodium in ethylenediamine at room temperature. The solid‐state structures of Na 4 (DME) 7.5 P 14 ( 1a ) and Na 4 (en) 6 P 14 ( 1b ) (DME = 1,2‐dimethoxyethane; en = ethylenediamine) are described.

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