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Facile Routes to Sodium Tetradecaphosphide Na 4 P 14 and Molecular Structure of Na 4 (DME) 7.5 P 14 and Na 4 (en) 6 P 14 (DME = 1,2‐dimethoxyethane; en = ethylenediamine)
Author(s) -
Miluykov Vasili,
Kataev Alexander,
Sinyashin Oleg,
Lönnecke Peter,
HeyHawkins Evamarie
Publication year - 2006
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600108
Subject(s) - ethylenediamine , dimethoxyethane , sodium , chemistry , inorganic chemistry , organic chemistry , electrode , electrolyte
Tetrasodium tetradecaphosphide Na 4 P 14 was obtained either from the reaction of PCl 3 with sodium in refluxing THF or from the reaction of red phosphorus and sodium in ethylenediamine at room temperature. The solid‐state structures of Na 4 (DME) 7.5 P 14 ( 1a ) and Na 4 (en) 6 P 14 ( 1b ) (DME = 1,2‐dimethoxyethane; en = ethylenediamine) are described.