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Molecular Structures of some Tellurium Derivatives of 1,2‐Dicarba‐ closo ‐dodecaborane(12)
Author(s) -
Herberhold Max,
Milius Wolfgang,
Jin GuoXin,
Kremnitz Walter,
Wrackmeyer Bernd
Publication year - 2006
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600100
Subject(s) - carborane , tellurium , chemistry , lithium (medication) , boron , carbon fibers , group 2 organometallic chemistry , stereochemistry , crystallography , molecule , organic chemistry , materials science , composite number , composite material , endocrinology , medicine
The insertion of tellurium into the carbon‐lithium bonds of lithiated ortho ‐carborane, C 2 B 10 H 12 , in solution can be used to generate organometallic derivatives with Te 2 units. In addition to di( ortho ‐carborane‐1‐yl) ditellane, (C 2 B 10 H 11 ) 2 Te 2 ( 2c ), two cylic compounds containing each two annellated [(dicarba‐ closo‐ dodecaborano)] units, (C 2 B 10 H 10 ) 2 Te 4 ( 3c ) and (C 2 B 10 H 10 ) 2 Te 2 (SnMe 2 ) ( 4c ), have been structurally characterized.