Synthesis and Structure of a Two‐dimensional Vanadium Tellurite, [H 2 en][VTeO 5 ] 2 | Zendy

Jung Kyungna | Zendy; Kim Hyejin | Zendy; Yun Hoseop | Zendy; Do Junghwan | Zendy

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Synthesis and Structure of a Two‐dimensional Vanadium Tellurite, [H 2 en][VTeO 5 ] 2

Author(s) -

Jung Kyungna,

Kim Hyejin,

Yun Hoseop,

Do Junghwan

Publication year - 2006

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200600066

Subject(s) - vanadium , ethylenediamine , square pyramidal molecular geometry , tetrahedron , crystallography , hydrothermal synthesis , unit (ring theory) , square (algebra) , hydrothermal circulation , hydrogen bond , materials science , chemistry , crystal structure , inorganic chemistry , molecule , mathematics , geometry , chemical engineering , mathematics education , organic chemistry , engineering

[H 2 en][VTeO 5 ] 2 (en = ethylenediamine) was synthesized by a hydrothermal reaction and structurally charac terized. The structure of [H 2 en][VTeO 5 ] 2 consists of an infinite [VTeO 5 ] − layer, which contains VO 4 tetrahedral and TeO 5 square pyramidal units. Two square pyramidal TeO 5 units are connected by sharing an edge to form a Te 2 O 8 binuclear unit. The interlayer space is filled by diprotonated ethylenediammonium cations that link the layers through a network of hydrogen bonds.

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