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Ungewöhnliche Bildung und Struktur eines O‐Sulfinato‐Zinkkomplexes
Author(s) -
Ibrahim Mohamed M.,
Vahrenkamp Heinrich
Publication year - 2006
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600009
Subject(s) - zinc , chemistry , inert gas , organic chemistry
Abstract Unusual Formation and Structure of a O‐Sulfinato Zinc Complex Whereas the reaction between hydrotris[(N‐xylyl)‐thioimidazolyl]borato‐zinc perchlorate ([ L· Zn‐OClO 3 ]) and ethanethiolate under an inert atmosphere leads to the thiolate complex [ L· Zn‐SC 2 H 5 ], the same reaction in air produces the sulfinato complex [ L· Zn‐O‐S(O)‐C 2 H 5 ] ( 1 ). 1 is the first fully characterized sulfinato‐zinc complex. Its structure determination has confirmed the unusual coordination of the sulfinato ligand via one of its oxygen atoms.