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Die Reaktion von AlCl mit H 2 O in festem Argon: IR‐matrixspektroskopischer Nachweis von HAl(Cl)OH
Author(s) -
Köppe R.
Publication year - 2006
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200600006
Subject(s) - toluene , chemistry , argon , molecule , ether , condensation , medicinal chemistry , polymer chemistry , organic chemistry , physics , thermodynamics
The Reaction of AlCl with H 2 O in Solid Argon: IR Matrixspectroscopic Detection of HAl(Cl)OH After photolytical activation of AlCl and H 2 O in solid argon the molecule HAl(Cl)OH is formed. Structure and bonding is characterized by means of normal coordinate analysis and quantum chemical calculations. The complex AlCl···H 2 O formed directly after condensation serves as a model system for the stabilisation of aluminium monohalide in a mixture of toluene and ether.