Die Reaktion von AlCl mit H 2 O in festem Argon: IR‐matrixspektroskopischer Nachweis von HAl(Cl)OH | Zendy

Köppe R. | Zendy

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Die Reaktion von AlCl mit H 2 O in festem Argon: IR‐matrixspektroskopischer Nachweis von HAl(Cl)OH

Author(s) -

Köppe R.

Publication year - 2006

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200600006

Subject(s) - toluene , chemistry , argon , molecule , ether , condensation , medicinal chemistry , polymer chemistry , organic chemistry , physics , thermodynamics

The Reaction of AlCl with H 2 O in Solid Argon: IR Matrixspectroscopic Detection of HAl(Cl)OH After photolytical activation of AlCl and H 2 O in solid argon the molecule HAl(Cl)OH is formed. Structure and bonding is characterized by means of normal coordinate analysis and quantum chemical calculations. The complex AlCl···H 2 O formed directly after condensation serves as a model system for the stabilisation of aluminium monohalide in a mixture of toluene and ether.

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