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Synthesis and Characterization of Monomeric Aryloxo Palladium Complexes of the Type [Pd(N–N)(OAr)(C 6 F 5 )].Crystal Structure of [Pd(tmeda)(C 6 F 5 )(OC 6 H 4 NO 2 ‐ p )]
Author(s) -
Ruiz José,
Martínez M. Teresa,
Vicente Consuelo,
Rodríguez Venancio,
López Gregorio,
Pérez José,
Chaloner Penny A.,
Hitchcock Peter B.
Publication year - 2005
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200570048
Subject(s) - tetrahydrofuran , palladium , tetramethylethylenediamine , crystal structure , chemistry , crystallography , hydrogen bond , monomer , intermolecular force , crystal (programming language) , stereochemistry , medicinal chemistry , molecule , catalysis , polymer , organic chemistry , solvent , computer science , programming language
Mononuclear palladium‐hydroxo complexes of the type [Pd(N–N)(C 6 F 5 )(OH)][(N–N) = 2,2′‐bipyridine (bipy), 4,4′‐dimethyl‐2,2′‐bipyridine (Me 2 bipy), 1,10‐phenantroline (phen) or N,N,N′,N′‐tetramethylethylenediamine (tmeda) react with phenols ArOH in tetrahydrofuran giving the corresponding aryloxo complexes [Pd(N–N)(C 6 F 5 )(OAr)]. Elemental analyses and spectroscopic (IR, 1 H and 19 F) methods have been used to characterize the new complexes. The X‐ray crystal structure of [Pd(tmeda)(C 6 F 5 )(OC 6 H 4 NO 2 ‐ p )] has been determined. In the crystal packing the planes defined by two C 6 H 4 rings show a parallel orientation. There are also intermolecular C–H···F and C‐H···O hydrogen bonds.