A Structural Study of the Solid Solution Eu 2 (Mo 1‐x W x ) 3 O 12 | Zendy

Boulahya K. | Zendy; Parras M. | Zendy; GonzálezCalbet J. M. | Zendy

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A Structural Study of the Solid Solution Eu 2 (Mo 1‐x W x ) 3 O 12

Author(s) -

Boulahya K.,

Parras M.,

GonzálezCalbet J. M.

Publication year - 2005

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200570039

Subject(s) - solid solution , scheelite , crystallography , x ray crystallography , diffraction , electron diffraction , tetrahedron , materials science , chemistry , tungsten , physics , metallurgy , optics

A structural study by means of X‐ray and electron diffraction of intermediate oxides between Eu 2 Mo 3 O 12 and Eu 2 W 3 O 12 shows the existence of a new Eu 2 (Mo 1−x W x ) 3 O 12 solid solution with the scheelite structural type. The essential feature of the x = 1/3 and x = 2/3 compounds is the presence of isolated oxygen tetrahedra, in which, according to X‐ray and electron diffraction data, W and Mo are randomly distributed. Eu atoms occupy distorted square antiprisms sites.

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