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Synthesis and Structures of the Ligands 1‐Methylimidazol‐2‐yl(pyridin‐2‐yl)methanone {(py)(mim)CO} and 1‐Benzylimidazol‐2‐yl(1‐phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO) 4 (L 2 ‐ N , N′ )]
Author(s) -
Batten Michael P.,
Canty Allan J.,
Cavell Kingsley J.,
Skelton Brian W.,
White Allan H.
Publication year - 2006
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200500531
Subject(s) - denticity , octahedron , chemistry , molybdenum , ligand (biochemistry) , medicinal chemistry , stereochemistry , coordination complex , crystallography , crystal structure , inorganic chemistry , receptor , organic chemistry , metal , biochemistry
Abstract The complexes [Mo(CO) 4 (L 2 ‐ N,N′ )] [L 2 = 1‐methylimidazol‐2‐yl(pyridin‐2‐yl)methanone and 1‐benzylimidazol‐2‐yl(1‐phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen‐donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis ‐bidentate ligand configurations.