Synthesis and Structures of the Ligands 1‐Methylimidazol‐2‐yl(pyridin‐2‐yl)methanone {(py)(mim)CO} and 1‐Benzylimidazol‐2‐yl(1‐phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO) 4 (L 2 ‐ N ,  N′ )] | Zendy

Batten Michael P. | Zendy; Canty Allan J. | Zendy; Cavell Kingsley J. | Zendy; Skelton Brian W. | Zendy; White Allan H. | Zendy

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Synthesis and Structures of the Ligands 1‐Methylimidazol‐2‐yl(pyridin‐2‐yl)methanone {(py)(mim)CO} and 1‐Benzylimidazol‐2‐yl(1‐phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO) 4 (L 2 ‐ N , N′ )]

Author(s) -

Batten Michael P.,

Canty Allan J.,

Cavell Kingsley J.,

Skelton Brian W.,

White Allan H.

Publication year - 2006

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200500531

Subject(s) - denticity , octahedron , chemistry , molybdenum , ligand (biochemistry) , medicinal chemistry , stereochemistry , coordination complex , crystallography , crystal structure , inorganic chemistry , receptor , organic chemistry , metal , biochemistry

The complexes [Mo(CO) 4 (L 2 ‐ N,N′ )] [L 2 = 1‐methylimidazol‐2‐yl(pyridin‐2‐yl)methanone and 1‐benzylimidazol‐2‐yl(1‐phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen‐donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis ‐bidentate ligand configurations.

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