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Synthesis and Structure of Potassium 1‐Benzylimidazole‐2‐carboxylate · 2/3Hydrate
Author(s) -
Batten Michael P.,
Canty Allan J.,
Cavell Kingsley J.,
Skelton Brian W.,
White Allan H.
Publication year - 2006
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200500519
Subject(s) - potassium , carboxylate , chemistry , crystallography , crystal structure , stereochemistry , organic chemistry
The title compound, K[bimCO 2 ] · 2/3H 2 O (C 11 H 19 N 2 O 2 K · 2/3H 2 O), has been synthesized, and characterized by a single crystal X‐ray study; it has the grouping $\rm [K_{3}(bimCO_{2})_{3}(OH_{2})_{2}]_{(\infty/\infty)}$ cross‐linked into a polymeric sheet in which potassium environments are diverse and unsymmetrical, containing six‐coordinate and seven‐coordinate geometries.
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