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Ruthenium(II)‐Komplexe mit orthometallierten O'Donnell Schiffbasen (Diphenylmethylenglycinester) [1]
Author(s) -
Urban Reinhold,
Beck Wolfgang
Publication year - 2006
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200500465
Subject(s) - ruthenium , chemistry , methylene , glycine , medicinal chemistry , stereochemistry , catalysis , organic chemistry , amino acid , biochemistry
Ruthenium(II) Complexes of Orthometallated O'Donnell Schiff Bases (Diphenylmethylene Glycine Esters) [1] The reaction of diphenyl methylene glycine esters with [Ru(PPh 3 ) 3 Cl 2 ] gives the orthometallated complexes [Ru(PPh 3 ) 2 (Cl){(C 6 H 4 )(C 6 H 5 )C=NCH 2 CO 2 R}] (R = H, Et, CMe 3 ) in which the ester group is coordinated to the ruthenium atom and which were characterized by IR, NMR, MS data and by cyclovoltammetry.