Thermal and Structural Studies of a 1D Zinc(II) Coordination Polymer – [Zn(μ‐4,4′‐bipy)(H 2 O) 4 ] n (CCl 3 COO) 2n ·(4,4′‐bipy) 2n  (4,4′‐bipy = 4,4′‐bipyridine), with Shorted Cl···Cl Interactions | Zendy

Amiri Maryam Ghoreishi | Zendy; Morsali Ali | Zendy

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Thermal and Structural Studies of a 1D Zinc(II) Coordination Polymer – [Zn(μ‐4,4′‐bipy)(H 2 O) 4 ] n (CCl 3 COO) 2n ·(4,4′‐bipy) 2n (4,4′‐bipy = 4,4′‐bipyridine), with Shorted Cl···Cl Interactions

Author(s) -

Amiri Maryam Ghoreishi,

Morsali Ali

Publication year - 2006

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200500412

Subject(s) - stacking , octahedron , zinc , crystallography , polymer , coordination polymer , chemistry , hydrogen bond , solid state , inorganic chemistry , materials science , molecule , crystal structure , organic chemistry

A 1D Zn II (μ‐4,4′‐bipy) coordination polymer with trichloroacetate anions, [Zn(4,4′‐bipy)(H 2 O) 4 ] n (CCl 3 COO) 2n ·(4,4′‐bipy) 2n , has been synthesized, characterized and studied by thermal and X‐ray crystallography. The structural studies show the Zn atoms have a distorted octahedral environment. Self‐assembly of this compound in the solid state is likely caused by hydrogen boding, shorted Cl···Cl and π‐π stacking interactions.

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