Answer to the Comment submitted by R. Niewa and D. A. Zherebtsov on the Paper “Synthesis and Electrochemical Study of Antifluorite‐type Phases in the Li‐M‐N‐O (M = Ti, V) Systems” [1] | Zendy

Palacín M. R. | Zendy

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Answer to the Comment submitted by R. Niewa and D. A. Zherebtsov on the Paper “Synthesis and Electrochemical Study of Antifluorite‐type Phases in the Li‐M‐N‐O (M = Ti, V) Systems” [1]

Author(s) -

Palacín M. R.

Publication year - 2006

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200500404

Subject(s) - lithium (medication) , neutron diffraction , electrochemistry , fluorite , crystallography , type (biology) , vanadium , order (exchange) , solid solution , materials science , diffraction , chemistry , inorganic chemistry , crystal structure , physics , electrode , metallurgy , medicine , ecology , finance , economics , optics , biology , endocrinology

In the reaction conditions leading to γ‐Li 7 VN 4 , no ordered solid solution γ‐Li 7 VN 4 –Li 2 O seems to exist but rather a mixture of two phases: γ‐Li 7 VN 4 and a lithium vanadium oxynitride with the disordered anti‐fluorite structure. Even though the trend may be different in the case of β‐Li 7 VN 4 –Li 2 O, neutron diffraction experiments would be desirable to confirm/dismiss these assumptions, as they would allow to determine the number of phases and polymorphs present and the degree of Li/V or N/O order, if any.

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