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[ p ‐ t Bu‐calix[4](OMe) 2 (OBeCl) 2 ]: The First Structually Characterized Beryllium Calixarene Complex
Author(s) -
Gottfriedsen Jochen,
Blaurock Steffen
Publication year - 2005
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200500328
Subject(s) - calixarene , beryllium , chemistry , solid state , stereochemistry , medicinal chemistry , crystallography , molecule , organic chemistry
Treatment of [ p ‐ t Bu‐calix[4](OMe) 2 (OLi) 2 ] with two equivalents of BeCl 2 gave the unprecedented dinuclear beryllium complex [ p ‐ p ‐ t Bu‐calix[4](OMe) 2 (OBeCl) 2 ], which was structurally characterized, both in solution (NMR) and in the solid state (X‐ray structure analysis).