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Zinc(II) and Cadmium(II) Complexes of the 3‐(2‐Pyridyl)‐5,6‐diphenyl‐1,2,4‐triazine (PDPT) Ligand, Structural Studies of [Zn(PDPT) 2 Cl(ClO 4 )] and [Cd(PDPT) 2 (NO 3 )(ClO 4 )]
Author(s) -
Marandi Farzin,
Soudi Ali Akbar,
Morsali Ali,
Kempe Rhett
Publication year - 2005
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200500268
Subject(s) - perchlorate , chemistry , cadmium , zinc , ligand (biochemistry) , triazine , crystallography , inorganic chemistry , medicinal chemistry , ion , polymer chemistry , organic chemistry , biochemistry , receptor
Two new mixed‐anion zinc(II) and cadmium(II) complexes of 3‐(2‐pyridyl)‐5,6‐diphenyl‐1,2,4‐triazine (PDPT) ligand, [Zn(PDPT) 2 Cl(ClO 4 )] and [Cd(PDPT) 2 (NO 3 )(ClO 4 )], have been synthesized and characterized by elemental analysis, IR‐ and 1 H NMR spectroscopy. The single crystal X‐ray analyses show that the coordination number in these complexes is six with four N‐donor atoms from two “PDPT” ligand and two of the anionic ligands, ZnN 4 ClO perchlorate , CdN 4 O nitrate O perchlorate . Self‐assembly of these compounds in the solid state via π – π ‐stacking interactions is discussed.