Wasserstoffbrücken in 1,1‐Bis(2‐hydroxyethyl)‐3‐benzoylthioharnstoff und seinen Nickel(II)‐ und Kupfer(II)‐Chelat‐Komplexen | Zendy

Cornejo Jorge Angulo | Zendy; Ayala Ketty | Zendy; Richter Rainer | Zendy; Böhlig Heinz | Zendy; Hennig Lothar | Zendy; Beyer Lothar | Zendy

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Wasserstoffbrücken in 1,1‐Bis(2‐hydroxyethyl)‐3‐benzoylthioharnstoff und seinen Nickel(II)‐ und Kupfer(II)‐Chelat‐Komplexen

Author(s) -

Cornejo Jorge Angulo,

Ayala Ketty,

Richter Rainer,

Böhlig Heinz,

Hennig Lothar,

Beyer Lothar

Publication year - 2005

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.200500266

Subject(s) - nickel , chemistry , intramolecular force , copper , hydrogen bond , chelation , molecule , ligand (biochemistry) , polymer chemistry , medicinal chemistry , inorganic chemistry , crystallography , stereochemistry , organic chemistry , receptor , biochemistry

Hydrogen Bonds in 1,1‐Bis(2‐hydroxyethyl)‐3‐benzoylthiourea and its Nickel(II)‐ and Copper(II)‐Chelate Complexes The ligand 1,1‐bis(2‐hydroxyethyl)‐3‐benzoylthiourea HL, ( 1 ), yields with nickel(II) and copper(II) ions neutral complexes [NiL 2 ], ( 2 ), and [CuL 2 ], ( 3 ). By X‐ray structure analysis and IR spectroscopy different intramolecular hydrogen bonds (OH…O) and (OH…N) could be identified in both equally coordinated ligands of the [NiL 2 ] molecule. For comparison X‐ray and IR data were also estimated for 1 and 3 .

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