Premium
[ p ‐ t Bu‐calix[4](OMe) 2 (O) 2 Ce(acac) 2 ]: A Calix[4]arene Stabilized Cerium(IV) Complex
Author(s) -
Gottfriedsen Jochen
Publication year - 2005
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200500222
Subject(s) - cerium , toluene , chemistry , medicinal chemistry , calixarene , inorganic chemistry , molecule , organic chemistry
Ce(acac) 4 (acac = acetylacetonate) reacts with p ‐ t Bu‐calix[4](OMe) 2 (OH) 2 ( 1 ) in toluene to give the new cerium(IV) calix[4]arene complex [ p ‐ t Bu‐calix[4](OMe) 2 (O) 2 Ce(acac) 2 ] ( 2 ). The compound has been fully characterized by elemental analysis, spectroscopic methods and X‐ray single crystal structure analysis.