Premium
Hydrothermal Synthesis, Structure, and Magnetic Properties of a Three‐dimensional Polymeric Ni II Complex, [Ni(bpp)(NIP)(H 2 O)] n (bpp = 1,3‐di(4‐pyridyl)propane, NIP = 5‐nitroisophthalate)
Author(s) -
Xiao HongPing,
Wang JiaGuo,
Li XinHua,
Morsali Ali
Publication year - 2005
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200500199
Subject(s) - nip , nickel , crystallography , antiferromagnetism , octahedron , stacking , propane , ligand (biochemistry) , hydrothermal circulation , atom (system on chip) , chemistry , materials science , stereochemistry , crystal structure , metallurgy , physics , condensed matter physics , organic chemistry , biochemistry , receptor , computer science , composite material , embedded system , seismology , geology
A three‐dimensional polymeric Ni II complex, [Ni(bpp)(NIP)(H 2 O)] n (bpp = 1,3‐di(4‐pyridyl)propane and NIP = 5‐nitroisophthalate), has been synthesized and characterized. The coordination number of the nickel atom is six (NiN 2 O 4 ) and the coordination environment around the Ni II atom may be described as a distorted octahedron in which two nitrogen atoms of “bpp” ligand occupy the cis positions. The effective magnetic moment for this complex indicate that the interactions between two Ni II atoms through the effective exchange media are antiferromagnetic. Self‐assembly of these compounds in the solid state via π–π‐stacking interactions is discussed.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom