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Synthese und Kristallstruktur von 2‐Azido‐4,6‐dichloro‐ s ‐triazin
Author(s) -
Gibson Katharina,
Tragl Sonja,
Meyer H.Jürgen
Publication year - 2005
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200500187
Subject(s) - orthorhombic crystal system , crystal structure , azide , cyanuric chloride , crystallography , triazine , sodium azide , chemistry , molecule , stereochemistry , polymer chemistry , organic chemistry
Synthesis and Crystal Structure of 2‐Azido‐4,6‐dichloro‐ s ‐triazine Single crystals of 2‐azido‐4,6‐dichloro‐ s ‐triazine were obtained from a reaction between cyanuric chloride and sodium azide. The structure of this compound was determined by single crystal X‐ray diffraction. 2‐Azido‐4,6‐dichloro‐ s ‐triazine crystallizes in the orthorhombic space group Pbca (no. 61), Z = 8, a = 746.48(8) pm, b = 952.6(1) pm, c = 2001.6(2) pm. The crystal structure contains (C 3 N 3 )(N 3 )Cl 2 molecules being arranged in a tape‐like fashion, with tapes running along a‐axis direction. The tapes are combined with each other by interlocking azide‐ligands including an angle of approximately 90°. This arrangement leads to the formation of corrugated layers in the crystal structure.