Premium
Synthesis and Characterization of Et 2 NM{OB[OSi(O t Bu) 3 ] 2 } 3 (M = Zr, Hf) Molecular Precursors to Zr/B/Si/O and Hf/B/Si/O Materials
Author(s) -
Fujdala Kyle L.,
Tilley T. Don
Publication year - 2005
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.200500128
Subject(s) - ligand (biochemistry) , oxide , chemistry , transition metal , characterization (materials science) , stereochemistry , crystallography , medicinal chemistry , materials science , nanotechnology , catalysis , organic chemistry , receptor , biochemistry
Two new transition metal complexes containing the –OB[OSi(O t Bu) 3 ] 2 ligand, Et 2 NM{OB[OSi(O t Bu) 3 ] 2 } 3 (M = Zr, Hf), are reported. These species are the 4 th and 5 th examples of complexes containing this recently reported borosiloxide ligand. Their use as potential molecular precursors to multi‐component oxide materials via the thermolytic molecular precursor (TMP) method is discussed.